Solid Phase Adsorption Toxin Tracking
(SPATT) technology for field monitoring
of Gambierdiscus toxins with passive
samplers
Ciguatera poisoning is a seafood intoxication classically associated with
the consumption of tropical coral reef
fish contaminated with ciguatoxins
(CTXs), although some marine invertebrates such as bivalves, gastropods or
echinoids are also potential vectors of
ciguatera [1-3]. CTXs are polyether neurotoxins produced by dinoflagellates of
the genera Gambierdiscus and Fukuyoa,
and are responsible for severe acute
digestive, neurological, and cardiovascular symptoms in humans [4]. Ciguatera has major health and economic impacts on vulnerable island communities
whose subsistence strongly relies on
the sustainable exploitation of marine
resources, such as in the Pacific island
countries and territories (PICTs) where
high incidence rates have been consistently reported in the past two decades
[5].
Most surveillance programmes currently rely on the survey of cell densities
and species composition of Gambierdiscus populations, as well as on the evaluation of CTXs concentrations in marine
products. However, such methods are
time consuming and expensive, thus
emphasizing the need for supplementary tools, based on the spatio-temporally
integrated sampling of dissolved algal
toxins directly in marine environments.
The SPATT (solid phase adsorption toxin tracking) technology, first introduced
in 2004 [6], uses porous synthetic resins
capable of adsorbing dissolved toxins
directly from the water column (Fig. 1).
Numerous laboratory and field studies,
testing different adsorbent substrates
of which Diaion HP20 resin appears to
be the most versatile substrate, have been
carried out worldwide to assess the applicability of these passive monitoring
devices to the detection of lipophilic
and hydrophilic toxins produced by a
variety of marine and freshwater microorganisms [7]. Regarding the monitoring of toxins associated with ciguatera,
one laboratory study has demonstrated
the efficacy of HP20 resin for the detection of dissolved CTXs and maitotoxins
(MTXs) in Gambierdiscus cultures [8].
The efficacy of SPATT technology
to detect Gambierdiscus toxins in the
field in ciguateric biotopes was recently
confirmed by the deployment of SPATT
devices filled with 10 g of HP20 resin
for 48 h in two French Polynesian sites:
main village of Kaukura Island (Tuamotu archipelago) and Anaho Bay in Nuku
Hiva Island (Marquesas archipelago),
characterized by a moderate vs. high
risk of ciguatera [9]. The presence of
CTXs in SPATT devices was assessed
using the neuroblastoma cell-based
assay (CBA-N2a) and results showed
that SPATT devices deployed in Anaho
Bay were able to retain 1.30 0.41 ng
P-CTX3C equiv. g-1 HP20 resin. Liquid
chromatography - tandem mass spectrometry (LC-MS/MS) analyses confirmed that P-CTX3B and P-CTX3C were
primarily retained on SPATT devices.
These results are coherent with environmental observations that confirmed
the presence of significant amounts of
Gambierdiscus cells in Anaho Bay, most
notably in the species G. polynesiensis
known for its very high toxic potential,
and with toxicological analyses that
demonstrated the presence of CTXs
in all marine products tested [2,3]. In
contrast, no CTXs were detected in
SPATT devices deployed in Kaukura
Island. However, as with SPATT devices deployed in Anaho Bay, LC-MS/
MS analyses revealed the adsorption
of a putative MTX analogue, known as
MTX3, on SPATT devices deployed in
Kaukura Island. Recent studies indicate
that putative MTX3 is ubiquitous within
Gambierdiscus genus [10], suggesting
its potential use as a biomarker of the
occurrence of Gambierdiscus cells in
the natural environment. Since a very
low density of Gambierdiscus cells was
observed in Kaukura Island, the detection of putative MTX3 but not of CTXs
on SPATT devices suggest either the
presence of non-toxic Gambierdiscus
Fig. 1. Example of a design of SPATT device assembly and field deployment. Left and middle: the SPATT device is made of two nylon mesh layers
filled with a porous synthetic resin (Diaion HP20, polystyrene-divinylbenzene matrix, is the most used resin), and fixed between two PVC
circular frames. Right: in the field, the SPATT device is inserted in plastic grids to prevent its damage and grazing by fish, and maintained in a
vertical position in the water column using weights and floats. M. Roué (modified from [7] and [9])
8
HARMFUL ALGAE NEWS NO. 60 / 2018
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Fig. 2. Summary of the results demonstrating that SPATT passive sampling could advantageously contribute to the reinforcement of ciguateric risk assessment and management programmes as a supplementary tool. or of very low densities of toxic Gambierdiscus cells. However, CTXs were detected in numero
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